Importance of Ion Packing on the Dynamics of Ionic Liquids during Micropore Charging
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چکیده
منابع مشابه
Importance of Ion Packing on the Dynamics of Ionic Liquids during Micropore Charging.
Molecular simulations of the diffusion of EMIM(+) and TFSI(-) ions in slit-shaped micropores under conditions similar to those during charging show that in pores that accommodate only a single layer of ions, ions diffuse increasingly faster as the pore becomes charged (with diffusion coefficients even reaching ∼5 × 10(-9) m(2)/s), unless the pore becomes very highly charged. In pores wide enoug...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry Letters
سال: 2015
ISSN: 1948-7185
DOI: 10.1021/acs.jpclett.5b02378